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1

Fundamental reactions of free radicals relevant to pyrolysis reactions

Marvin L. Poutsma

Journal:

Journal of Analytical and Applied Pyrolysis

Year:

2000

Language:

english

File:

PDF, 238 KB

english, 2000

2

Reduction of propargylic chlorides with tri-n-butyltin hydride. The ambident behavior of propargylic radicals

Fantazier, Richard Michael., Poutsma, Marvin L.

Journal:

Journal of the American Chemical Society

Year:

1968

Language:

english

File:

PDF, 1.10 MB

english, 1968

3

Free-radical model for coal conversions. Effect of conversion level and concentration on thermolysis of bibenzyl

Marvin L. Poutsma

Journal:

Year:

1980

Language:

english

File:

PDF, 490 KB

english, 1980

4

Carbon-14 tracer study of the fate of tetralin under simulated SRC-1 coal liquefaction conditions

Marvin L. Poutsma, E.Lloyd Youngblood, George E. Oswald, Henry D. Cochran

Journal:

Year:

1982

Language:

english

File:

PDF, 880 KB

english, 1982

5

Comparison of literature models for volatile product formation from the pyrolysis of polyisobutylene at mild conditions: Data analysis, free-radical mechanistic considerations, and simulation of initial product-forming pathways

Marvin L. Poutsma

Journal:

Journal of Analytical and Applied Pyrolysis

Year:

2005

Language:

english

File:

PDF, 1.88 MB

english, 2005

6

Mechanistic analysis and thermochemical kinetic simulation of the products from pyrolysis of poly(α-methylstyrene), especially the unrecognized role of phenyl shift

Marvin L. Poutsma

Journal:

Journal of Analytical and Applied Pyrolysis

Year:

2007

Language:

english

File:

PDF, 308 KB

english, 2007

7

Mechanistic analysis and thermochemical kinetic simulation of the pathways for volatile product formation from pyrolysis of polystyrene, especially for the dimer

Marvin L. Poutsma

Journal:

Polymer Degradation and Stability

Year:

2006

Language:

english

File:

PDF, 1.00 MB

english, 2006

8

Further considerations of the sources of the volatiles from pyrolysis of polystyrene

Marvin L. Poutsma

Journal:

Polymer Degradation and Stability

Year:

2009

Language:

english

File:

PDF, 296 KB

english, 2009

9

Addition of hydrogen chloride to an allylidenecyclopropane; survival of the cyclopropane ring

Marvin L. Poutsma, Pedro A. Ibarbia

Journal:

Tetrahedron Letters

Year:

1970

Language:

english

File:

PDF, 173 KB

english, 1970

10

Reaction of 3-methyl-1-butyne and 3-methyl-1,2-butadiene witht-butyl hypochlorite: propargyl and methyleneallyl radicals

Marvin L. Poutsma

Journal:

Tetrahedron Letters

Year:

1969

Language:

english

File:

PDF, 215 KB

english, 1969

11

Disproportionation of anthracene in molten antimony trichloride by simultaneous hydrogenation and scholl condensation reactions

Marvin L. Poutsma, Arthur S. Dworkin, Jorulf Brynestad, Lloyd L. Brown, B.M. Benjamin, G.Pedro Smith

Journal:

Tetrahedron Letters

Year:

1978

Language:

english

File:

PDF, 232 KB

english, 1978

12

Competitive atom transfer and rearrangement reactions of 2,2,2-triphenylethyl radical

Marvin L. Poutsma, Pedro A. Ibarbia

Journal:

Tetrahedron Letters

Year:

1972

Language:

english

File:

PDF, 237 KB

english, 1972

13

Comparison of mechanistic models for correlation of activation energies of liquid-phase addition of carbon-centered radicals to terminal olefins

Marvin L. Poutsma

Journal:

Journal of Physical Organic Chemistry

Year:

2008

Language:

english

File:

PDF, 498 KB

english, 2008

14

Chain elongation during thermolysis of tetrafluoroethylene and hexafluoropropylene: Modeling of mechanistic hypotheses and elucidation of data needs

Marvin L. Poutsma

Journal:

Journal of Analytical and Applied Pyrolysis

Year:

2011

Language:

english

File:

PDF, 1.00 MB

english, 2011

15

Review of Rate Constants and Exploration of Correlations of the Halogen Transfer Reaction of Trisubstituted Carbon-Centered Radicals with Molecular Halogens

Poutsma, Marvin L.

Journal:

Journal of Organic Chemistry

Year:

2012

Language:

english

File:

PDF, 766 KB

english, 2012

16

Free-radical thermolysis and hydrogenolysis of model hydrocarbons relevant to processing of coal

Poutsma, Marvin L.

Journal:

Year:

1990

Language:

english

File:

PDF, 2.43 MB

english, 1990

17

Notes: Clemmensen Reduction of Acetophenone

Poutsma, Marvin, Wolthuis, Enno

Journal:

Journal of Organic Chemistry

Year:

1959

Language:

english

File:

PDF, 401 KB

english, 1959

18

The Radical Stabilization Energy of a Substituted Carbon-Centered Free Radical Depends on Both the Functionality of the Substituent and the Ordinality of the Radical

Poutsma, Marvin L.

Journal:

Journal of Organic Chemistry

Year:

2011

Language:

english

File:

PDF, 984 KB

english, 2011

19

Evolution of Structure–Reactivity Correlations for the Hydrogen Abstraction Reaction by Chlorine Atom

Poutsma, Marvin L.

Journal:

Journal of Physical Chemistry A

Year:

2013

Language:

english

File:

PDF, 1.13 MB

english, 2013

20

Electrophilic additions to 2-methyl-1-(tetramethylcyclopropylidene) propene. Generation of cyclopropylidenecarbinyl cations

Poutsma, Marvin L., Ibarbia, Pedro A.

Journal:

Journal of the American Chemical Society

Year:

1971

Language:

english

File:

PDF, 1.36 MB

english, 1971

21

Comparison of thermal cracking of the isomeric hexanes with that catalyzed by potassium ion exchanged Y zeolite

Poutsma, Marvin L., Schaffer, Sherry R.

Journal:

Journal of Physical Chemistry

Year:

1973

Language:

english

File:

PDF, 1.12 MB

english, 1973

22

Chlorination Studies of Unsaturated Materials in Nonpolar Media. III. Competition between Ionic and Free-Radical Reactions during Chlorination of the Isomeric Butenes and Allyl Chloride 1

Poutsma, Marvin L.

Journal:

Journal of the American Chemical Society

Year:

1965

Language:

english

File:

PDF, 1.43 MB

english, 1965

23

Evaluation of the Kinetic Data for Intramolecular 1, x -Hydrogen Shifts in Alkyl Radicals and Structure/Reactivity Predictions from the Carbocyclic Model for the Transition State

Poutsma, Marvin L.

Journal:

Journal of Organic Chemistry

Year:

2007

Language:

english

File:

PDF, 206 KB

english, 2007

24

Radical addition of protonated N-chloropiperidine to conjugated enynes

Poutsma, Marvin L., Ibarbia, Pedro A.

Journal:

Journal of Organic Chemistry

Year:

1971

Language:

english

File:

PDF, 441 KB

english, 1971

25

Additions and Corrections - Chlorination Studies of Unsaturated Materials in Nonpolar Media. IV. The Ionic Pathway for Alkylated Ethylenes. Products and Relative Reactivities.

Poutsma, Marvin

Journal:

Journal of the American Chemical Society

Year:

1965

Language:

english

File:

PDF, 72 KB

english, 1965

26

Thermal cleavage reactions of N-chloroketimines. Behavior of imino radicals

Poutsma, Marvin L., Ibarbia, Pedro A.

Journal:

Journal of Organic Chemistry

Year:

1969

Language:

english

File:

PDF, 1.12 MB

english, 1969

27

Choice of Bond Dissociation Enthalpies on Which To Base the Stabilization Energies of Simple Radicals: DH(R−H) Is Preferred Because DH(R−Me) and DH(R−R) Are Perturbed by Changes in Chain Branching

Poutsma, Marvin L.

Journal:

Journal of Organic Chemistry

Year:

2008

Language:

english

File:

PDF, 186 KB

english, 2008

28

Chlorination Studies of Unsaturated Materials in Nonpolar Media. II. Competition between Ionic and Free-Radical Reactions during Chlorination of Cyclohexene 1

Poutsma, Marvin L.

Journal:

Journal of the American Chemical Society

Year:

1965

Language:

english

File:

PDF, 1.35 MB

english, 1965

29

Rearrangements of Benzeneazotribenzoylmethane and its Derivatives. Structural Reassignments

Curtin, David Y., Poutsma, Marvin L.

Journal:

Journal of the American Chemical Society

Year:

1962

Language:

english

File:

PDF, 826 KB

english, 1962

30

Rearrangements of Benzeneazotribenzoylmethane. 1 1,3-benzoyl Migrations from Carbon to Oxygen and from Carbon to Nitrogen

Curtin, David Y., Poutsma, Marvin L.

Journal:

Journal of the American Chemical Society

Year:

1962

Language:

english

File:

PDF, 1.01 MB

english, 1962

31

Reexamination of the Pyrolysis of Polyethylene: Data Needs, Free-Radical Mechanistic Considerations, and Thermochemical Kinetic Simulation of Initial Product-Forming Pathways

Poutsma, Marvin L.

Journal:

Year:

2003

Language:

english

File:

PDF, 399 KB

english, 2003

32

Thermolysis of model compounds for coal. 4. Modification of the free-radical thermolysis of bibenzyl by surface immobilization

Poutsma, Marvin L., Douglas, Emily C., Leach, Janie E.

Journal:

Journal of the American Chemical Society

Year:

1984

Language:

english

File:

PDF, 317 KB

english, 1984

33

Chlorination Studies of Unsaturated Materials in Nonpolar Media. V. Norbornene and Nortricyclene 1

Poutsma, Marvin L.

Journal:

Journal of the American Chemical Society

Year:

1965

Language:

english

File:

PDF, 1011 KB

english, 1965

34

Radical addition of trimethyltin hydride to conjugated enynes

Poutsma, Marvin L., Ibarbia, Pedro A.

Journal:

Journal of the American Chemical Society

Year:

1973

Language:

english

File:

PDF, 1.17 MB

english, 1973

35

Chlorination studies of unsaturated materials in nonpolar media. VIII. Ionic chlorination of some simple allenes

Poutsma, Marvin L.

Journal:

Journal of Organic Chemistry

Year:

1968

Language:

english

File:

PDF, 699 KB

english, 1968

36

Solvent and salt effects on the products from polar chlorination of the linear pentenes

Poutsma, Marvin L., Kartch, Joan L.

Journal:

Journal of the American Chemical Society

Year:

1967

Language:

english

File:

PDF, 1.28 MB

english, 1967

37

Correction. Chlorination of Unsaturated Material in Nonpolar Media. VII. Butadiene: a Reevaluation.

Poutsma, Marvin

Journal:

Journal of Organic Chemistry

Year:

1967

Language:

english

File:

PDF, 165 KB

english, 1967

38

Radical Addition of tert-Butyl Hypochlorite to Conjugated Enynes

Poutsma, Marvin, Ibarbia, Pedro

Journal:

Journal of Organic Chemistry

Year:

1970

Language:

english

File:

PDF, 1.36 MB

english, 1970

39

10.1021/ja00904a054

Poutsma, Marvin L.

Journal:

Journal of the American Chemical Society

Year:

1963

Language:

english

File:

PDF, 286 KB

english, 1963

40

Correction. Radical Addition of tert-Butyl Hypochlorite to Conjugated Enynes

Poutsma, Marvin, Ibarbia, Pedro

Journal:

Journal of Organic Chemistry

Year:

1971

Language:

english

File:

PDF, 133 KB

english, 1971

41

Progress toward the Mechanistic Description and Simulation of the Pyrolysis of Tetralin

Poutsma, Marvin L.

Journal:

Year:

2002

Language:

english

File:

PDF, 454 KB

english, 2002

42

Evolution of Structure–Reactivity Correlations for the Hydrogen Abstraction Reaction by Hydroxyl Radical and Comparison with That by Chlorine Atom

Poutsma, Marvin L.

Journal:

Journal of Physical Chemistry A

Year:

2013

Language:

english

File:

PDF, 1.30 MB

english, 2013

43

Thermolysis of model compounds for coal. 2. Condensation and hydrogen transfer during thermolysis of naphthols

Poutsma, Marvin L., Dyer, Catherine W.

Journal:

Journal of Organic Chemistry

Year:

1982

Language:

english

File:

PDF, 1.41 MB

english, 1982

44

Thermolysis of model compounds for coal. 3. Radical chain decomposition of 1,3-diphenylpropane and 1,4-diphenylbutane

Poutsma, Marvin L., Dyer, Catherine W.

Journal:

Journal of Organic Chemistry

Year:

1982

Language:

english

File:

PDF, 1.60 MB

english, 1982

45

Thermolysis of model compounds for coal. Part 5. Enhancement of free-radical chain rearrangement, cyclization, and hydrogenolysis during thermolysis of surface-immobilized bibenzyl. Implications for coal chemistry

Buchanan, A. C., Dunstan, T. Don J., Douglas, Emily C., Poutsma, Marvin L.

Journal:

Journal of the American Chemical Society

Year:

1986

Language:

english

File:

PDF, 1.72 MB

english, 1986

46

Chlorination Studies of Unsaturated Materials in Nonpolar Media. IV. The Ionic Pathway for Alkylated Ethylenes. Products and Relative Reactivities 1

Poutsma, Marvin L.

Journal:

Journal of the American Chemical Society

Year:

1965

Language:

english

File:

PDF, 1.00 MB

english, 1965

47

Determination of the equivalent weight of metals: A freshman research project

Wolthuis, Enno, DeVries, Dale, Poutsma, Marvin

Journal:

Journal of Chemical Education

Year:

1957

Language:

english

File:

PDF, 1.94 MB

english, 1957

48

Extension of Structure–Reactivity Correlations for the Hydrogen Abstraction Reaction by Bromine Atom and Comparison to Chlorine Atom and Hydroxyl Radical

Poutsma, Marvin L.

Journal:

Journal of Physical Chemistry A

Year:

2016

Language:

english

File:

PDF, 520 KB

english, 2016

49

Comment on “Radicalicity: A scale to compare reactivities of radicals” (Chem. Phys. Lett. 618 (2015) 99–101)

Poutsma, Marvin L.

Journal:

Chemical Physics Letters

Year:

2016

Language:

english

File:

PDF, 191 KB

english, 2016

50

Chlorination of Unsaturated Materials in Nonpolar Media. VII. Butadiene: a Reevaluation 1

Poutsma, Marvin L.

Journal:

Journal of Organic Chemistry

Year:

1966

Language:

english

File:

PDF, 578 KB

english, 1966

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